fig4

Phase programming: microstructural design in rechargeable battery materials

Figure 4. Phase programming strategies toward enhanced cycling stability. (A) Schematic illustration of phase programming concepts for improving cycling stability; (B) Schematic diagram comparing the changes in materials with and without AlF3 coating after cycling[51]. Reprinted with permission from Ref.[51] Copyright © 2014 American Chemical Society; (C) Phase programming strategy using spinel nanodomains to relieve strain accumulation and suppress structural degradation[52]. Reprinted with permission from Ref.[52] Copyright © 2025 Elsevier; D) (Schematic illustration of twin boundaries mitigating lattice evolution and crack formation of ternary (NMC) materials during cycling[53]. Reprinted with permission from Ref.[53] Copyright © 2022 American Chemical Society.

Microstructures
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