fig5
Figure 5. (A) HCHO conversion (η) as a function of temperature (T) over x wt% Na-1 wt% Pt/TiO2 (x = 0, 1, and 2). Reaction conditions: 600 ppm HCHO, 20 vol% O2, 50% relative humidity, He (balance), total flow rate = 50 cm3/min, and SV = 120,000 h-1 (inset: stability test over 2 wt% Na-1 wt% Pt/TiO2 at 25 °C and SV = 300,000 h-1 under the same other reaction conditions); (B) H2-TPR profiles of x wt% Na-1% Pt/TiO2 (x = 0, 1, and 2)[54]. (A and B) adapted from reference[54]. Copyright 2012, John Wiley and Sons; (C) Electron density difference plots for the Pt-W structure. Blue represents an electron-loss region, and yellow represents an electron-accumulation region. The isosurface level is 0.01 e/Å3; PDOS plots for the (D) Pt sites in Pt nanoparticles, (E) Pt sites in PtW nanoparticles, and (F) W sites in PtW nanoparticles[62]. C−F adapted from reference[62]. Copyright 2026, Elsevier. PDOS: Projected density of states; H2-TPR: hydrogen temperature-programmed reduction.



